Novel coordination compounds: Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) cations with acesulfame/N,N-diethylnicotinamide ligands

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dc.authoridYILDIRIM, Tugrul/0000-0002-5681-6880
dc.authoridYildirim, Tugrul/0000-0002-2316-0766
dc.contributor.authorYildirim, Tugrul
dc.contributor.authorKose, Dursun Ali
dc.contributor.authorAvci, Guelcin Alp
dc.contributor.authorSahin, Onur
dc.contributor.authorAkkurt, Fatih
dc.date.accessioned2025-03-23T19:35:25Z
dc.date.available2025-03-23T19:35:25Z
dc.date.issued2019
dc.departmentSinop Üniversitesi
dc.description.abstractFive coordination complexes with Mn2+ (1), Co2+ (2), Ni2+ (3), Cu2+ (4), and Zn2+ (5) containing acesulfame (ace) and N,N-diethylnicotinamide (dena) ligands were synthesized and structural binding properties investigated. Four compounds (1, 2, 4, and 5) were examined with single crystal X-ray diffraction methods. The structures containing Mn(II), Co(II), and Zn(II) were iso-structural. Six-coordination of metal cations were completed with two moles dena and four aqua ligands. The dena ligands were coordinated via pyridine nitrogen as neutral-monodentate. Charge stabilities of the complexes are complemented by two moles monoanionic ace ligands, located outside of the coordination unit. In the Cu(II) complex, the coordination is completed by acidic nitrogen and carbonyl oxygen atoms of two ace ligands and pyridine nitrogen of two moles dena ligands. The coordination to Cu(II) for ace ligands was monoanionic-bidentate. All metal cations in the structure are distorted octahedral. Thermal decomposition of complexes begins with removal of the aqua molecules from the structures and is completed by combustion of organic ligands. The final decomposition products of all structures have been identified as corresponding metal oxides. Some biological applications (anti-fungal/anti-bacterial) were studied using 1-5.
dc.description.sponsorshipHitit University Unit of Scientific Research Projects [FEF19004.15.009]
dc.description.sponsorshipThe authors acknowledge Hitit University Unit of Scientific Research Projects (FEF19004.15.009) and Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer.
dc.identifier.doi10.1080/00958972.2019.1705970
dc.identifier.endpage3517
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue22-24
dc.identifier.scopus2-s2.0-85078441876
dc.identifier.scopusqualityQ3
dc.identifier.startpage3502
dc.identifier.urihttps://doi.org/10.1080/00958972.2019.1705970
dc.identifier.urihttps://hdl.handle.net/11486/5864
dc.identifier.volume72
dc.identifier.wosWOS:000508330200001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectAcesulfame
dc.subjectN
dc.subjectN-diethylnicotinamide
dc.subjectcoordination compounds
dc.subjectanti-microbial studies
dc.subjectstructural properties
dc.subjectthermal investigation
dc.titleNovel coordination compounds: Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) cations with acesulfame/N,N-diethylnicotinamide ligands
dc.typeArticle

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