Mono and dinuclear copper(II) naproxenato complexes containing 3-picoline and 4-picoline: synthesis, structure, properties, catechol oxidase, and antimicrobial activities

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dc.contributor.authorCaglar, Sema
dc.contributor.authorAdiguzel, Ekrem
dc.contributor.authorSariboga, Bahtiyar
dc.contributor.authorTemel, Ersin
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2025-03-23T19:35:26Z
dc.date.available2025-03-23T19:35:26Z
dc.date.issued2014
dc.departmentSinop Üniversitesi
dc.description.abstractMononuclear and dinuclear copper(II) complexes [Cu-2(mu-nap)(4)(3-pic)(2)] (1) and [Cu(nap)(2)(H2O)(4-pic)(2)] (2) have been synthesized in the presence of 3-picoline and 4-picoline. Two complexes were characterized by FT-IR, UV-vis spectroscopic methods and their thermal stabilities were determined by TG/DTA/DTG techniques. The crystal structures of 1 and 2 were established by X-ray analysis. X-ray structure analysis has shown that copper(II) has a distorted square-pyramidal geometry. Naproxenate is a bridging ligand in 1 and monodentate in 2. Two complexes have shown catalytic activity on oxidation of 3,5-di-tert-butylcatechol to 3,5-di-tert-butylquinone exhibiting saturation kinetics at high substrate concentrations. The complexes were also screened for antimicrobial activity against pathogenic bacteria and fungi. The complexes exhibited antimicrobial activity against Entrococcus faecalis and Candida albicans.
dc.description.sponsorshipErzincan University [110205]
dc.description.sponsorshipThis work was financially supported by the Erzincan University under project no. 110205.
dc.identifier.doi10.1080/00958972.2014.891198
dc.identifier.endpage683
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue4
dc.identifier.scopus2-s2.0-84899047985
dc.identifier.scopusqualityQ3
dc.identifier.startpage670
dc.identifier.urihttps://doi.org/10.1080/00958972.2014.891198
dc.identifier.urihttps://hdl.handle.net/11486/5871
dc.identifier.volume67
dc.identifier.wosWOS:000333954500010
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectCopper(II) complex
dc.subjectAntimicrobial activity
dc.subjectNaproxen
dc.subjectCatechol oxidation
dc.titleMono and dinuclear copper(II) naproxenato complexes containing 3-picoline and 4-picoline: synthesis, structure, properties, catechol oxidase, and antimicrobial activities
dc.typeArticle

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