Synthesis, spectroscopic and structural studies of 4-Amino-3-(ethyl)-5-(4-chlorophenyl)-4H-1,2,4-triazole and 4-Amino-3-cyclopropyl-5-oxo-4,5-dihydro-1,2,4-triazole-1-yl-acetic acid ethyl ester

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dc.authoridSasmaz, Selami/0000-0001-5311-7550
dc.authoridkantar, cihan/0000-0002-5234-0782
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorSahin, Onur
dc.contributor.authorKantar, Cihan
dc.contributor.authorSasmaz, Selami
dc.contributor.authorGumrukcuoglu, Nurhan
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2025-03-23T19:40:49Z
dc.date.available2025-03-23T19:40:49Z
dc.date.issued2014
dc.departmentSinop Üniversitesi
dc.description.abstractThe title compounds of 4-Amino-3-(ethyl)-5-(4-chlorophenyl)-4H-1,2,4-triazole (I, C10H11ClN4) and 4-Amino-3-cyclopropyl-5-oxo-4,5-dihydro-1,2,4-triazol-1-yl-acetic acid ethyl ester (II, C9H14N4O3), have been determined using X-ray diffraction techniques and characterized by IR, H-1 NMR and C-13 NMR. X-ray study shows that the title compounds both have strong intermolecular N-H center dot center dot center dot N hydrogen bonds. The molecules of! are linked into a two-dimensional framework structure by N-H center dot center dot center dot N and C-H center dot center dot center dot N hydrogen bonds which produce R-2(2)(8)R-4(4)(14)R-4(4)(15) chain of rings, while in II, the combination of N-H center dot center dot center dot N, N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds along [100] generates a chain of edge-fused R-2(2)(10)R-2(2)(16)R-4(2)(14)R-4(4)(14) rings. (C) 2014 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.molstruc.2014.03.022
dc.identifier.endpage87
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-84898457158
dc.identifier.scopusqualityQ1
dc.identifier.startpage83
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2014.03.022
dc.identifier.urihttps://hdl.handle.net/11486/6423
dc.identifier.volume1067
dc.identifier.wosWOS:000336342100010
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectSynthesis
dc.subjectCrystal structures
dc.subjectTriazole
dc.subjectHydrogen bonds
dc.titleSynthesis, spectroscopic and structural studies of 4-Amino-3-(ethyl)-5-(4-chlorophenyl)-4H-1,2,4-triazole and 4-Amino-3-cyclopropyl-5-oxo-4,5-dihydro-1,2,4-triazole-1-yl-acetic acid ethyl ester
dc.typeArticle

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