Synthesis and characterization of boric acid mediated metal-organic frameworks based on trimesic acid and terephthalic acid

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dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridOZER, Demet/0000-0003-0862-9607
dc.contributor.authorOzer, Demet
dc.contributor.authorKose, Dursun A.
dc.contributor.authorSahin, Onur
dc.contributor.authorOztas, Nursen Altuntas
dc.date.accessioned2025-03-23T19:39:37Z
dc.date.available2025-03-23T19:39:37Z
dc.date.issued2017
dc.departmentSinop Üniversitesi
dc.description.abstractThe new metal-organic framework materials based on boric acid reported herein. Sodium and boron containing metal-organic frameworks were synthesized by one-pot self-assembly reaction in the presence of trimesic acid and terephthalic acid in water/ethanol solution. Boric acid is a relatively cheap boron source and boric acid mediated metal-organic framework prepared mild conditions compared to the other boron source based metal-organic framework. The synthesized compounds were characterized by FT-IR, p-XRD, TGA/DTA, elemental analysis, C-13-MAS NMR, B-11-NMR and single crystal measurements. The molecular formulas of compounds were estimated as C18H33B2Na5O28 and C8H24B2Na2O17 according to the structural analysis. The obtained complexes were thermally stable. Surface properties of inorganic polymer complexes were investigated by BET analyses and hydrogen storage properties of compound were also calculated. (C) 2017 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.molstruc.2017.03.120
dc.identifier.endpage267
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85016571812
dc.identifier.scopusqualityQ1
dc.identifier.startpage261
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2017.03.120
dc.identifier.urihttps://hdl.handle.net/11486/6395
dc.identifier.volume1141
dc.identifier.wosWOS:000401593400032
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectBoric acid
dc.subjectSodium
dc.subjectTrimesic acid
dc.subjectTerephthalic acid
dc.subjectB-MOF
dc.titleSynthesis and characterization of boric acid mediated metal-organic frameworks based on trimesic acid and terephthalic acid
dc.typeArticle

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