N-Alkylation and N,C-Dialkylation of Amines with Alcohols in the Presence of Ruthenium Catalysts with Chelating N-Heterocyclic Carbene Ligands

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dc.authoridOzdemir, Ismail/0000-0001-6325-0216
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridbruneau, christian/0000-0002-2220-1458
dc.authoridACHARD, Mathieu/0000-0003-0578-9680
dc.authoridSAHIN, Zeynel/0000-0002-7719-7652
dc.contributor.authorSahin, Zeynel
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.contributor.authorAchard, Mathieu
dc.contributor.authorBruneau, Christian
dc.date.accessioned2025-03-23T19:35:48Z
dc.date.available2025-03-23T19:35:48Z
dc.date.issued2015
dc.departmentSinop Üniversitesi
dc.description.abstractA series of new benzimidazolium salts and ruthenium(II) complexes containing chelating N-heterocyclic carbenes (NHCs) functionalized with a benzylic group and an acetal group were prepared. All of the synthesized compounds were characterized by elemental analysis and NMR spectroscopy, and the molecular structures of 2c and 2d were determined by X-ray crystallography. All of the,complexes were tested in the alkylation of cyclic amine derivatives with alcohols and showed excellent activity in this reaction. Cyclic amines were alkylated with primary and heteroaromatic alcohols. The Ru-NHC Complexes also catalyzed N,C3-dialkylation of cyclic amines.
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey (TUBITAK) [112T303]; Inonu University Research Fund [I.U. B.A.P: 2014/Gudumlu-53]
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey (TUBITAK) (112T303) and the Inonu University Research Fund (I.U. B.A.P: 2014/Gudumlu-53).
dc.identifier.doi10.1021/om501066n
dc.identifier.endpage2304
dc.identifier.issn0276-7333
dc.identifier.issn1520-6041
dc.identifier.issue11
dc.identifier.scopus2-s2.0-84931270334
dc.identifier.scopusqualityQ2
dc.identifier.startpage2296
dc.identifier.urihttps://doi.org/10.1021/om501066n
dc.identifier.urihttps://hdl.handle.net/11486/5938
dc.identifier.volume34
dc.identifier.wosWOS:000356841800031
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.relation.ispartofOrganometallics
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectTransition-Metal-Complexes
dc.subjectTransfer Hydrogenation
dc.subjectSecondary Alcohols
dc.subjectBeta-Alkylation
dc.subjectStereodirecting Ligands
dc.subjectSelective Alkylation
dc.subjectRecyclable Catalyst
dc.subjectReductive Amination
dc.subjectEfficient Catalysts
dc.subjectAlkene Metathesis
dc.titleN-Alkylation and N,C-Dialkylation of Amines with Alcohols in the Presence of Ruthenium Catalysts with Chelating N-Heterocyclic Carbene Ligands
dc.typeArticle

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