Synthesis, crystal structure, and characterization of two heterometallic transition metal citrate complexes [M = Co(II) and Cd(II)]

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dc.authoridYAVUZ, Abdulkerim/0000-0001-5674-4429
dc.authoridKARTAL, Zeki/0000-0001-9739-0858
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorKartal, Zeki
dc.contributor.authorSahin, Onur
dc.contributor.authorYavuz, Abdulkerim
dc.date.accessioned2025-03-23T19:26:08Z
dc.date.available2025-03-23T19:26:08Z
dc.date.issued2019
dc.departmentSinop Üniversitesi
dc.description.abstractIn this study, two heterometallic transition metal complexes with the formulas [CoK4(mu(10)-C6H5O7)(2)](n) and [CdK(mu(8)-C6H5O7)(mu-H2O)(H2O)](n) were synthesized as crystalline compounds. The structures of these crystalline metal complexes were characterized by their spectral analyses (FT-IR, FT-Raman, thermal analysis, magnetic properties, and single-crystal X-ray diffraction techniques). According to the spectral data of the new metal complexes obtained, both metal complexes are in the monoclinic crystal system and in the P2(1)/c and P2(1) space groups, respectively. The asymmetric unit of the metal complex [CoK4(mu(10)-C6H5O7)(2)](n) contains one Co(II) ion, two potassium cations, and one (C6H5O7) citrate ligand, whereas that of the asymmetric unit of the metal complex [CdK(mu(8)-C6H5O7)(mu-H2O)(H2O)](n) contains one Cd(II) ion, one potassium cation, one (C6H5O7) citrate ligand, and two coordinated water molecules.
dc.description.sponsorshipDumlupinar University [2015/66]
dc.description.sponsorshipThe authors wish to thank in particular Dumlupinar University for the technical (Department of Physics and Chemistry) and financial support within the project numbered 2015/66. The authors also acknowledge the support of the Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer. The authors are grateful to the Central Research Laboratory Application and Research Center (BUMLAB), Bartin University, Turkey, for the use of the Hitachi STA 7300 thermal analyzer equipment.
dc.identifier.doi10.3906/kim-1808-38
dc.identifier.endpage+
dc.identifier.issn1300-0527
dc.identifier.issue2
dc.identifier.scopusqualityQ3
dc.identifier.startpage555
dc.identifier.trdizinid335626
dc.identifier.urihttps://doi.org/10.3906/kim-1808-38
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/335626
dc.identifier.urihttps://hdl.handle.net/11486/4640
dc.identifier.volume43
dc.identifier.wosWOS:000466785800016
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakTR-Dizin
dc.language.isoen
dc.publisherTubitak Scientific & Technological Research Council Turkey
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WOS_20250323
dc.subjectTransition metal complexes
dc.subjectsingle-crystal X-ray diffraction analysis
dc.subjectvibrational spectra
dc.subjectcitric acid
dc.subjectcitrate ion
dc.titleSynthesis, crystal structure, and characterization of two heterometallic transition metal citrate complexes [M = Co(II) and Cd(II)]
dc.typeArticle

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