Syntheses and Electrochemical Characterization of Low Oxidation Potential Nitrogen Analogs of Pedot as Electrochromic Materials

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dc.authoridGULLU, Mustafa/0000-0003-3905-1094
dc.authoridSoylemez, Saniye/0000-0002-8955-133X
dc.authoridYigit, Deniz/0000-0003-2211-7114
dc.authoridERMIS, EMEL/0000-0003-3052-4123
dc.contributor.authorHacioglu, Serife O.
dc.contributor.authorYigit, Deniz
dc.contributor.authorErmis, Emel
dc.contributor.authorSoylemez, Saniye
dc.contributor.authorGullu, Mustafa
dc.contributor.authorToppare, Levent
dc.date.accessioned2025-03-23T19:31:01Z
dc.date.available2025-03-23T19:31:01Z
dc.date.issued2016
dc.departmentSinop Üniversitesi
dc.description.abstractIn this study, the electropolymerization of ethyl andmethyl substituted asymmetrical nitrogen analogs of 3,4-ethylenedioxythiophene (OEt and OMe) were synthesized, characterized and their electrochemical properties were investigated. Both polymers (POEt and POMe) were synthesized electrochemically and characterized using spectroelectrochemical technique to determine optical changes of the resulting polymer films. Electrochemical studies demonstrated that these polymers exhibited a significantly low oxidation potential compared to their analogs reported in the literature. These polymers also provided a low optical bandgap with good optical contrasts. Furthermore, multi-electrochromic properties upon different applied potentials revealed that these polymers have potential applications in electrochromic devices. As a further characterization, their dual type electrochromic devices were constructed with poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PTMA) which is transmissive in its both redox states. Devices were characterized via electrochemical and spectroelectrochemical techniques. (C) 2016 The Electrochemical Society. All rights reserved.
dc.identifier.doi10.1149/2.0171610jes
dc.identifier.endpageE299
dc.identifier.issn0013-4651
dc.identifier.issn1945-7111
dc.identifier.issue10
dc.identifier.scopus2-s2.0-84987720660
dc.identifier.scopusqualityQ1
dc.identifier.startpageE293
dc.identifier.urihttps://doi.org/10.1149/2.0171610jes
dc.identifier.urihttps://hdl.handle.net/11486/5196
dc.identifier.volume163
dc.identifier.wosWOS:000389150900082
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElectrochemical Soc Inc
dc.relation.ispartofJournal of the Electrochemical Society
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectOrganic Semiconductors
dc.subjectConjugated Polymers
dc.subjectDerivatives
dc.subject3,4-Ethylenedioxythiophene
dc.subjectElectropolymerization
dc.subjectPerformance
dc.subjectThiophene
dc.subjectDevices
dc.subjectEdot
dc.titleSyntheses and Electrochemical Characterization of Low Oxidation Potential Nitrogen Analogs of Pedot as Electrochromic Materials
dc.typeArticle

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