Novel mixed ligand complexes of acesulfame / nicotinamide with some transition metals. Synthesis, crystal structural characterization, and biological properties

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dc.authoridOZER, Demet/0000-0003-0862-9607
dc.authoridAVCI, EMRE/0000-0003-1046-8208
dc.authoridYildirim, Tugrul/0000-0002-2316-0766
dc.authoridYILDIRIM, Tugrul/0000-0002-5681-6880
dc.contributor.authorYildirim, Tugrul
dc.contributor.authorKose, Dursun Ali
dc.contributor.authorAvci, Emre
dc.contributor.authorOzer, Demet
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:39:36Z
dc.date.available2025-03-23T19:39:36Z
dc.date.issued2019
dc.departmentSinop Üniversitesi
dc.description.abstractThe salt type mixed ligand metal complexes of COII (I), Ni-II (II), Cu-II (III), Zn-II (IV) and Mn-II (V) were synthesized using neutral ligand nicotinamide and anionic ligand acesulfame. The structural characterizations of complexes were performed by using elemental analysis, magnetic susceptibility, solid-state UV-Vis, FUR spectra, thermoanalytic TG-DTG/DTA, and single crystal X-ray diffraction methods. The complexes of I, III, IV, and V were obtained suitable crystal form for single crystal analysis by SC-XRD diffraction. The complexes of II was believed that the others structures so, the spectroscopic results of all the complexes are suitable for each other. The complexes are salt type compounds, and they have 2 mol nicotinamide ligands as monodentate coordination to metal center by pyridine N atoms and 4 mol aqua ligands in coordination sphere and 2 mol anionic acesulfamate ligands located outside of coordination unit as a counter ion. The metal(II) cationic atoms in complexes have octahedral geometry. Thermal decomposition steps of compounds are started with dehydration. (C) 2018 Published by Elsevier B.V.
dc.description.sponsorshipHitit University Unit of Scientific Research Projects [FEF19004.15.009]; Scientific and Technological Research Application and Research Center, Sinop University, Turkey
dc.description.sponsorshipThe authors acknowledge Hitit University Unit of Scientific Research Projects (FEF19004.15.009) and Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer.
dc.identifier.doi10.1016/j.molstruc.2018.08.099
dc.identifier.endpage582
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85054713426
dc.identifier.scopusqualityQ1
dc.identifier.startpage576
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2018.08.099
dc.identifier.urihttps://hdl.handle.net/11486/6378
dc.identifier.volume1176
dc.identifier.wosWOS:000449310600056
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectMixed ligand complexes
dc.subjectBiological application
dc.subjectAcesulfame
dc.subjectNicotinamide
dc.subjectCrystal structure
dc.subjectThermal properties
dc.titleNovel mixed ligand complexes of acesulfame / nicotinamide with some transition metals. Synthesis, crystal structural characterization, and biological properties
dc.typeArticle

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