Two-Dimensional Heteronuclear Coordination Polymers Constructed by Cyanide and 3-(2-Aminoethyl)pyridine Ligands

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dc.authoridKURKCUOGLU, GUNES SUHEYLA/0000-0003-3945-3085
dc.contributor.authorKurkcuoglu, Gunes Suheyla
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorSayin, Elvan
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:44:13Z
dc.date.available2025-03-23T19:44:13Z
dc.date.issued2021
dc.departmentSinop Üniversitesi
dc.description.abstractTwo new heteronuclear (Ni/Cd and Pd/Cd) 2D coordination polymers formulated as namely {[Cd(mu-3aepy)(2)Ni(mu-CN)(2)(CN)(2)].2H(2)O}(n)(1) and [Cd(3aepy)Pd(mu(4)-CN)(4)](n)(2) (3aepy = 3-(2-aminoethyl)pyridine) were obtained and determined using different techniques (FT-IR and Raman spectroscopies, single crystal X-ray diffraction, elemental, SEM-EDX and thermal analyses). Single crystal X-ray study of the complexes revealed that the Ni(II) and Pd(II) ions are coordinated with four cyanide-carbon atoms in square planar geometries. The Cd(II) ions are bridged by 3aepy ligands to generate [Cd-2(3aepy)(2)](2+)cation and adjacent cations are further linked to cyanide ligands from [Ni(mu-CN)(4)](2-)anion, generating corrugated rectangular grid-like 2D sheets in1. Whereas, the Cd(II) and Pd(II) ions are bridged by cyanide ligands, generating corrugated rectangular grid-like 2D sheets in2. The Cd1 is possessed the distorted octahedral coordination geometry with six nitrogen atoms from two 3aepy and four cyanide ligands. The Cd2 is coordinated by four nitrogen atoms from cyanide ligands to form a square-planar geometry. Furthermore, the most remarkable properties of the complexes are the existence of the intermolecular C-HMIDLINE HORIZONTAL ELLIPSISM interactions between M(II) and hydrogen atoms of the 3aepy ligands (M(II) = Ni and Pd).
dc.description.sponsorshipEskisehir Osmangazi University, Scientific research Unit [2018-2068]
dc.description.sponsorshipThe authors are highly thankful to the Eskisehir Osmangazi University, Scientific research Unit (Grant No: 2018-2068). Furthermore, the authors acknowledge to Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer.
dc.identifier.doi10.1007/s10904-020-01724-1
dc.identifier.endpage120
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.issue1
dc.identifier.scopus2-s2.0-85090196923
dc.identifier.scopusqualityQ1
dc.identifier.startpage112
dc.identifier.urihttps://doi.org/10.1007/s10904-020-01724-1
dc.identifier.urihttps://hdl.handle.net/11486/6903
dc.identifier.volume31
dc.identifier.wosWOS:000565859300001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materials
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectTetracyanonickelate(II) complex
dc.subjectTetracyanopalladate(II) complex
dc.subject3-(2-aminoethyl)pyridine complex
dc.subjectCyanide complex
dc.subjectC-HMIDLINE HORIZONTAL ELLIPSISNi interaction
dc.subjectC-HMIDLINE HORIZONTAL ELLIPSISPd interaction
dc.titleTwo-Dimensional Heteronuclear Coordination Polymers Constructed by Cyanide and 3-(2-Aminoethyl)pyridine Ligands
dc.typeArticle

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