Cyanide bridged hetero-metallic polymeric complexes: Syntheses, vibrational spectra, thermal analyses and crystal structures of complexes [M(1,2-dmi)2Ni(μ-CN)4]n (M = Zn(II) and Cd(II))

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dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridKURKCUOGLU, GUNES SUHEYLA/0000-0003-3945-3085
dc.contributor.authorKurkcuoglu, Gunes Suheyla
dc.contributor.authorSayin, Elvan
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:40:47Z
dc.date.available2025-03-23T19:40:47Z
dc.date.issued2015
dc.departmentSinop Üniversitesi
dc.description.abstractTwo cyanide bridged hetero-metallic complexes of general formula, (M(1,2-dmi)(2)Ni(mu-CN)(4)](n) (1,2-dmi = 1,2-dimethylimidazole and M = Zn(II) or Cd(II)) have been synthesized and characterized by vibrational (FT-IR and Raman) spectroscopy, single crystal X-ray diffraction, thermal analyses and elemental analyses. The crystallographic analyses reveal that the complexes, [Zn(1,2-dmi)(2)Ni(mu-CN)(4)] (1) and [Cd(1,2-dmi)(2)Ni(mu-CN)(4)] (2), have polymeric 2D networks. In the complexes, four cyanide groups of [Ni(CN)(4)](2-) coordinated to the adjacent M(II) ions and distorted octahedral geometries of complexes are completed by two nitrogen atoms of trans 1,2-dmi ligands. The structures of I and 2 are similar and linked via intermolecular hydrogen bonding, C-H center dot center dot center dot Ni interactions to give rise to 3D networks. Vibration assignments are given for all the observed bands and the spectral features also supported to the crystal structures of heteronuclear complexes. The FT-IR and Raman spectra of the complexes are very much consistent with the structural data presented. (c) 2015 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.molstruc.2015.08.013
dc.identifier.endpage90
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-84939817994
dc.identifier.scopusqualityQ1
dc.identifier.startpage82
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2015.08.013
dc.identifier.urihttps://hdl.handle.net/11486/6414
dc.identifier.volume1101
dc.identifier.wosWOS:000361863200012
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectTetracyanonickelate(II) complex
dc.subject1,2-dimethylimidazole complex
dc.subjectFT-IR and Raman spectra
dc.subjectThermal analyses
dc.subjectCrystal structure
dc.titleCyanide bridged hetero-metallic polymeric complexes: Syntheses, vibrational spectra, thermal analyses and crystal structures of complexes [M(1,2-dmi)2Ni(μ-CN)4]n (M = Zn(II) and Cd(II))
dc.typeArticle

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