Syntheses, crystal structures, spectroscopic and thermal properties of 3D heteronuclear coordination polymers with 4-ethylpyridine and cyanide ligands

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dc.authoridKURKCUOGLU, GUNES SUHEYLA/0000-0003-3945-3085
dc.contributor.authorKekec, Seray
dc.contributor.authorKurkcuoglu, Gunes Suheyla
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:44:02Z
dc.date.available2025-03-23T19:44:02Z
dc.date.issued2024
dc.departmentSinop Üniversitesi
dc.description.abstractThree new hexacyanometallate(III) complexes, namely {[Cd-3(4epy)(12)Cr-2(mu-CN)(6)(CN)(6)]center dot 4H(2)O}n (1), {[Cd-3(4epy)(12)Fe-2(mu-CN)(6)(CN)(6)]center dot 4H(2)O}n (2) and {[Cd-3(4epy)(12)Co-2(mu-CN)(6)(CN)(6)]center dot 4H(2)O}n (3), were synthesized by using 4-ethylpyridine (4epy) ligand and characterized by spectral (FT-IR and Raman), crystallographic (SC-XRD and PXRD), thermal and elemental analyses techniques. Single crystal studies have shown that heterometallic complexes 1-3 form 3D polymers. Each M ion [M = Cr(III) in 1, Fe(III) in 2 and Co(III) in 3] is coordinated by six carbon atoms from cyanide ligands and adjacent metal ions are bridged by cyanide ligands to generate [Cd6M6(CN)(12)] clusters. Each Cd(II) ion is coordinated by four nitrogen atoms from 4epy ligands and two nitrogen atoms from cyanide ligands to distorted octahedral coordination geometry. In addition, thermal (TG/DTA) properties of the complexes were investigated. Powder X-ray diffraction (PXRD) patterns of the complexes were recorded to control the phase purities.
dc.description.sponsorshipEskiscedil;ehir Osmangazi University, Scientific research Unit [2022-2561]
dc.description.sponsorshipThis work has been financially supported by Eski & scedil;ehir Osmangazi University, Scientific research Unit [grant no: 2022-2561].
dc.identifier.doi10.1007/s11224-023-02249-2
dc.identifier.endpage1083
dc.identifier.issn1040-0400
dc.identifier.issn1572-9001
dc.identifier.issue4
dc.identifier.scopus2-s2.0-85175691106
dc.identifier.scopusqualityQ2
dc.identifier.startpage1075
dc.identifier.urihttps://doi.org/10.1007/s11224-023-02249-2
dc.identifier.urihttps://hdl.handle.net/11486/6853
dc.identifier.volume35
dc.identifier.wosWOS:001103034300001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer/Plenum Publishers
dc.relation.ispartofStructural Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectHexacyanochromate(III)
dc.subjectHexacyanoferrate(III)
dc.subjectHexacyanocobaltate(III)
dc.subject4-ethylpyridine
dc.subjectCadmium(II)
dc.subject3D
dc.subjectCoordination polymers
dc.titleSyntheses, crystal structures, spectroscopic and thermal properties of 3D heteronuclear coordination polymers with 4-ethylpyridine and cyanide ligands
dc.typeArticle

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