Palladium Complexes with Tetrahydropyrimidin-2-ylidene Ligands: Catalytic Activity for the Direct Arylation of Furan, Thiophene, and Thiazole Derivatives

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dc.authoridyasar, sedat/0000-0001-7285-2761
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridKARACA, EMINE OZGE/0000-0003-2094-9742
dc.authoridDoucet, Henri/0000-0002-1410-3663
dc.authoridOzdemir, Ismail/0000-0001-6325-0216
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.contributor.authorKaraca, Emine Ozge
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorDoucet, Henri
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2025-03-23T19:35:48Z
dc.date.available2025-03-23T19:35:48Z
dc.date.issued2015
dc.departmentSinop Üniversitesi
dc.description.abstractThe synthesis and characterization of novel 1,3-benzyl-3,4,5,6-tetrahydropyrimidin-2-ylidene-based N-hetero-cyclic carbene palladium(II) complexes (1a-d) were described. The crystal structure of trans-dichlorobis[1,3-bis(4-methylbenzyl)-3,4,5,6-tetrahydropyrimidin-2-ylidend- palladium(II) was presented. Pd(II) complexes 1a-d were tested as catalysts in the direct C5 or C2 arylation of furans, thiophenes, and thiazoles, with various aryl bromides at 150 degrees C for 1 h. These complexes exhibited moderate to high catalytic activities under the given conditions.
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK-BOSPHORUS (France) [109T605]; TUBA; Inonu University Research Fund [I.U. B.A.P: 2013/51]
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK-BOSPHORUS (France) [109T605], TUBA, and Inonu University Research Fund (I.U. B.A.P: 2013/51).
dc.identifier.doi10.1021/om501201r
dc.identifier.endpage2493
dc.identifier.issn0276-7333
dc.identifier.issn1520-6041
dc.identifier.issue11
dc.identifier.scopus2-s2.0-84935870521
dc.identifier.scopusqualityQ2
dc.identifier.startpage2487
dc.identifier.urihttps://doi.org/10.1021/om501201r
dc.identifier.urihttps://hdl.handle.net/11486/5937
dc.identifier.volume34
dc.identifier.wosWOS:000356841800051
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.relation.ispartofOrganometallics
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectN-Heterocyclic-Carbene
dc.subjectC-H Functionalization
dc.subjectCross-Coupling Reactions
dc.subjectDirect C-2 Arylation
dc.subjectBond Formation
dc.subjectAryl Halides
dc.subjectRoom-Temperature
dc.subjectAzoles
dc.subjectEfficient
dc.subjectChlorides
dc.titlePalladium Complexes with Tetrahydropyrimidin-2-ylidene Ligands: Catalytic Activity for the Direct Arylation of Furan, Thiophene, and Thiazole Derivatives
dc.typeArticle

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