Study of structural, surface and hydrogen storage properties of boric acid mediated metal (sodium)-organic frameworks

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dc.authoridOZER, Demet/0000-0003-0862-9607
dc.contributor.authorOzer, Demet
dc.contributor.authorKose, Dursun A.
dc.contributor.authorSahin, Onur
dc.contributor.authorOztas, Nursen A.
dc.date.accessioned2025-03-23T19:39:36Z
dc.date.available2025-03-23T19:39:36Z
dc.date.issued2018
dc.departmentSinop Üniversitesi
dc.description.abstractThree boric acid mediated metal organic frameworks were synthesized by solution method with using succinic acid, fumaric acid and acetylene dicarboxylic acid as a ligand source and sodium as a metal source. The complexes were characterized by FT-IR, powder XRD, elemental analyses and single crystal measurements. The complexes with the formula, C4H18B2Na2O14, C4H16B2Na2O14 and C4H14B2Na2O14 were successfully obtained. BET surface area of complexes were calculated and found as 13.474 m(2)/g for catena-(tetrakis(mu 2-hydroxo)-(mu 2-trihydrogen borate)-(mu 2-succinato)-di-sodium boric acid solvate), 1.692 m(2)/g for catena-(tetralds(mu 2-hydroxo)-(mu 2-trihydrogen borate)-(mu 2-fumarato)-di-sodium boric acid solvate) and 5.600 m(2)/g for catena-(tetrakis(mu 2-hydroxo)-(mu 2-trihydrogen borate)-(mu 2-acetylenedicarboxylato)-di-sodium boric acid solvate). Hydrogen storage capacities of the complexes were also studied at 77 K 1 bar pressure and found as 0.108%, 0.033%, 0.021% by mass. When different ligands were used, the pore volume, pore width and surface area of the obtained complexes were changed. As a consequence, hydrogen storage capacities also changed. (C) 2017 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.molstruc.2017.12.063
dc.identifier.endpage164
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85038836788
dc.identifier.scopusqualityQ1
dc.identifier.startpage159
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2017.12.063
dc.identifier.urihttps://hdl.handle.net/11486/6388
dc.identifier.volume1157
dc.identifier.wosWOS:000425197400019
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectSodium
dc.subjectB-MOF
dc.subjectSuccinic acid
dc.subjectFumaric acid
dc.subjectAcetylene dicarboxylic acid
dc.subjectHydrogen storage
dc.titleStudy of structural, surface and hydrogen storage properties of boric acid mediated metal (sodium)-organic frameworks
dc.typeArticle

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