A New Photoluminescent and Antibacterial Polymeric Silver(I) Complex Generated from Pyridine-2,3-dicarboxylic Acid

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dc.authoridTOPCU, YILDIRAY/0000-0002-2095-6603
dc.authoridHamamci Alisir, Sevim/0000-0001-7296-8318
dc.contributor.authorAlisir, Sevim Hamamci
dc.contributor.authorSariboga, Bahtiyar
dc.contributor.authorTopcu, Yildiray
dc.contributor.authorYang, Shi-Yao
dc.date.accessioned2025-03-23T19:44:13Z
dc.date.available2025-03-23T19:44:13Z
dc.date.issued2013
dc.departmentSinop Üniversitesi
dc.description.abstractA new two-dimensional polymeric [Ag-2(mu-Hpydc)(2)(mu-pyz)](n) (1) (H (2) pydc = pyridine-2,3-dicarboxylic acid, pyz = pyrazine), has been synthesized and characterized by elemental analysis, IR spectroscopy, thermal analysis and single crystal X-ray diffraction. X-ray diffraction analyses show that Hpydc exhibits novel coordination mode in 1, acts as a bridging ligand between two Ag(I) centers via deprotonated carboxylate mu-O1 atoms, forming binuclear [Ag-2(mu-Hpydc)(2)] units (Ag center dot center dot center dot Ag separation is 2.9482(4) ). These units are connected to each other through pyz and Hpydc ligands, leading to two-dimensional polymeric structure. The coordination geometry around the silver(I) ions in the complex is a highly distorted square-pyramidal (tau = 0.229) with an AgN2O3 chromospheres. The solid state photoluminescence properties of 1 and H (2) pydc have been studied at room temperature. Furthermore, the complex has been tested for its in vitro antibacterial activity and is determined to be highly effective for antibacterial activity against Gram-positive and Gram-negative pathogenic bacteria cells. A new polymeric 2D silver(I) complex [Ag-2(mu-Hpydc)(2)(mu-pyz)](n) (1) (H (2) pydc = pyridine-2,3-dicarboxylic acid, pyz = pyrazine) has been synthesized and characterized by elemental analysis, IR spectroscopy, thermal analysis and single crystal X-ray diffraction. The solid state photoluminescence properties of 1 and H (2) pydc have been studied at room temperature and also it has been tested for its in vitro antibacterial activity.
dc.description.sponsorshipOndokuz Mayis University [PYO.MUH.1904.11.015]
dc.description.sponsorshipThe authors are grateful to the Research Fund of Ondokuz Mayis University (Project No. PYO.MUH.1904.11.015) for financial support of this work. We also thank Assoc. Prof. Okan Zafer Yesilel for his assistance and Fatih Semerci in obtaining the luminescence spectra.
dc.identifier.doi10.1007/s10904-013-9887-9
dc.identifier.endpage1067
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.issue5
dc.identifier.scopus2-s2.0-84881022706
dc.identifier.scopusqualityQ1
dc.identifier.startpage1061
dc.identifier.urihttps://doi.org/10.1007/s10904-013-9887-9
dc.identifier.urihttps://hdl.handle.net/11486/6904
dc.identifier.volume23
dc.identifier.wosWOS:000322667700003
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materials
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectSilver(I) complex
dc.subject2D coordination polymer
dc.subjectPyridine-2
dc.subject3-Dicarboxylate complex
dc.subjectAntibacterial activity
dc.subjectPhotoluminescent silver complex
dc.titleA New Photoluminescent and Antibacterial Polymeric Silver(I) Complex Generated from Pyridine-2,3-dicarboxylic Acid
dc.typeArticle

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