Immobilized Polyoxomolybdate Nanoclusters on Functionalized SBA-15: Green Access to Efficient and Recyclable Nanocatalyst for the Epoxidation of Alkenes

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dc.authoridAkbayrak, Serdar/0000-0003-3858-2985
dc.authoridOzkar, Saim/0000-0002-6302-1429
dc.contributor.authorBagherzadeh, Mojtaba
dc.contributor.authorHosseini, Hadighehsadat
dc.contributor.authorAkbayrak, Serdar
dc.contributor.authorOzkar, Saim
dc.date.accessioned2025-03-23T19:47:06Z
dc.date.available2025-03-23T19:47:06Z
dc.date.issued2019
dc.departmentSinop Üniversitesi
dc.description.abstractA heterogeneous nanocatalyst containing polyoxomolybdate immobilized on the internal surface of amino-functionalized SBA-15 pores was prepared and fully characterized by several analytical techniques. The textural property of supported material was found to retain important mesoporous features, compatible with its potential use as heterogeneous catalysts. The catalyst SBA-15-NH3+center dot{Mo-36}(-)shows excellent catalytic activity for the epoxidation of alkenes as compared to POM, which is attributed to the large specific surface area and highly ordered pore structure of SBA-15, allowing for easy access of reactants to the active sites and removal of products. The prepared catalyst has high recyclability performance without obvious loss of activity after six runs of epoxidation.
dc.description.sponsorshipResearch Council of Sharif University of Technology; Turkish Academy of Sciences
dc.description.sponsorshipFinancial support of this study was provided by the Research Council of Sharif University of Technology. Partial support by Turkish Academy of Sciences is also gratefully acknowledged.
dc.identifier.doi10.1002/slct.201900756
dc.identifier.endpage5917
dc.identifier.issn2365-6549
dc.identifier.issue19
dc.identifier.scopus2-s2.0-85066245954
dc.identifier.scopusqualityQ3
dc.identifier.startpage5911
dc.identifier.urihttps://doi.org/10.1002/slct.201900756
dc.identifier.urihttps://hdl.handle.net/11486/7283
dc.identifier.volume4
dc.identifier.wosWOS:000468976000073
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-V C H Verlag Gmbh
dc.relation.ispartofChemistryselect
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectEpoxidation
dc.subjectMesoporous nanomaterials
dc.subjectPolyoxomolybdate
dc.subjectSBA-15
dc.titleImmobilized Polyoxomolybdate Nanoclusters on Functionalized SBA-15: Green Access to Efficient and Recyclable Nanocatalyst for the Epoxidation of Alkenes
dc.typeArticle

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