Synthesis, characterization, photoluminescent properties and antimicrobial activities of two novel polymeric silver(I) complexes with diclofenac

Basit Öğe Kaydı
dc.authoridHamamci Alisir, Sevim/0000-0001-7296-8318
dc.contributor.authorAlisir, Sevim Hamamci
dc.contributor.authorSariboga, Bahtiyar
dc.contributor.authorCaglar, Sema
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2025-03-23T19:39:37Z
dc.date.available2025-03-23T19:39:37Z
dc.date.issued2017
dc.departmentSinop Üniversitesi
dc.description.abstractTwo novel silver(l) complexes with diclofenac, ({2-(2,6-dicholoroanilino)phenylacetic acid} = did) namely [Ag(dicl)](n) (1) and [Ag(dicl)(bipy)](n) (2) (bipy: 4,4'-bipyridine), have been synthesized and characterized by elemental analysis, IR spectroscopy, thermal analysis and single-crystal X-ray diffraction. X-ray crystallographic data of 1 revealed that did anion adopts a mu(3)-eta(1),eta(2) coordinated mode link three Ag atoms generate 1D infinite chain structure. In 2, did ligand plays crucial role to form double ladder chain structure, clamping two neighboring [Ag(mu-bipy)](infinity), chains by using carboxylate oxygen atoms (O1, O2). The most interesting structural feature of 2 is the presence of strong pi center dot center dot center dot pi interactions between aromatic phenyl rings of did placed in the adjacent 1D chains, leads to forming 2D slab structure. The coordination modes of did in the title complexes are supported by using IR spectroscopy. Thermal stabilities of 1 and 2 have been determined by TG/DTA/DTG techniques. The luminescent properties of complex 1 and 2 have been investigated in the solid state at room temperature. Furthermore, the title complexes have been tested for their in vitro antibacterial activities and are determined to be highly effective for antibacterial activity against Gram(+) and Gram(-) pathogenic bacteria cells. 1 and 2 showed activity on Fungi, as well. (C) 2016 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.molstruc.2016.10.026
dc.identifier.endpage164
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-84991716594
dc.identifier.scopusqualityQ1
dc.identifier.startpage156
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2016.10.026
dc.identifier.urihttps://hdl.handle.net/11486/6401
dc.identifier.volume1130
dc.identifier.wosWOS:000390731800020
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectSilver(I) complex
dc.subjectDiclofenac
dc.subjectCrystal structure
dc.subjectPhotoluminescence
dc.subjectAntibacterial activity
dc.titleSynthesis, characterization, photoluminescent properties and antimicrobial activities of two novel polymeric silver(I) complexes with diclofenac
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu