Zinc(II) and Cadmium(II) coordination polymers constructed from phenylenediacetate ligands

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dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridYESILEL, Okan Zafer/0000-0002-2284-1578
dc.authoridErer, Hakan/0000-0003-3540-8797
dc.contributor.authorSezer, Gunes Gunay
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorErer, Hakan
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:40:58Z
dc.date.available2025-03-23T19:40:58Z
dc.date.issued2016
dc.departmentSinop Üniversitesi
dc.description.abstractA series of new coordination polymers {[Zn(mu-opda)(mu-bpa)] center dot 2H(2)O}(n), (1), [Zn(mu(3)-ppda)(mu-bpa)](n) (2), [Cd(mu(3)-ppda)(mu-bPa)](n) (3), [Cd(mu(3)-mPda)(mu-bpa)](n), (4) and [Cd(mu(3)-mpda)(mu-bipy)](n) (5), (o/m/ppda=1,2/1,3/1,4-phenylenediacetate, bpa=1,2-bi(4-pyridyl)ethane, bipy=4,4'-bipyridine) were synthesized. Their structures were characterized by elemental analysis, IR spectroscopy, single-crystal and powder X-ray diffraction. Furthermore, the effect of metal sources (zinc acetate and zinc oxide) and acidity of the solution on the structure of the coordination polymers was discussed for complexes 1 and 5, respectively. The single-crystal X-ray crystallographic studies revealed that complexes 1, 3, 4 and 5 are uninodal (4) connected 2D frameworks and display sql topology with the point symbol of (4(4).6(2)). Complex 2 is 3D coordination polymer and exhibits pcu topology with the point symbol of (4(12).6(3)). In addition, the luminescent properties and thermal behavior of all complexes were also investigated. (C) 2015 Elsevier Inc. All rights reserved.
dc.description.sponsorshipThe Scientific and Technological Research Council of Turkey (TUBITAK), Turkey [1649B031402373]
dc.description.sponsorshipThis work has been supported by The Scientific and Technological Research Council of Turkey (TUBITAK, No: 1649B031402373), Turkey.
dc.identifier.doi10.1016/j.jssc.2015.11.025
dc.identifier.endpage470
dc.identifier.issn0022-4596
dc.identifier.issn1095-726X
dc.identifier.scopus2-s2.0-84947967215
dc.identifier.scopusqualityQ1
dc.identifier.startpage463
dc.identifier.urihttps://doi.org/10.1016/j.jssc.2015.11.025
dc.identifier.urihttps://hdl.handle.net/11486/6474
dc.identifier.volume233
dc.identifier.wosWOS:000369881200063
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAcademic Press Inc Elsevier Science
dc.relation.ispartofJournal of Solid State Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectCoordination polymer
dc.subjectPhenylenediacetate complex
dc.subjectZinc(II) complex
dc.subjectCadmium(II) complex
dc.subjectN-donor ligand
dc.titleZinc(II) and Cadmium(II) coordination polymers constructed from phenylenediacetate ligands
dc.typeArticle

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