Synthesis, spectroscopic, thermal and structural properties of 4-(2-aminoethyl)pyridinium tetracyanometallate(II) complexes

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dc.authoridKURKCUOGLU, GUNES SUHEYLA/0000-0003-3945-3085
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorKaraagac, Dursun
dc.contributor.authorKurkcuoglu, Gunes Suheyla
dc.contributor.authorSenyel, Mustafa
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:39:37Z
dc.date.available2025-03-23T19:39:37Z
dc.date.issued2017
dc.departmentSinop Üniversitesi
dc.description.abstractIn this study, three new complexes (4aepyH)(2)[Ni(CN)(4)] (1), (4aepyH)(2)[Pd(CN)(4)] (2) and (4aepyH)(2)[Pt(CN)(4)] (3) [4aepy = 4-(2-aminoethyl)pyridine] have been synthesized and characterized by elemental, thermal, vibrational (FT-IR and Raman) and single-crystal X-ray diffraction techniques. The crystallographic analyses reveal that the complexes crystallize in the monoclinic system, space group C2/c. The asymmetric units of the complexes contain one M(II) ion, two cyanide ligands and one non coordinated the 4aepy ligand. Each M(II) ion is four coordinated with four cyanide-carbon atoms in a square planar geometry and the [M(CN)(4)](2-) anions act as a counter ion. The 4aepyH cations in the complexes compose of the protonation of the 4aepy. The vibrational spectral data also supported to the crystal structures of the complexes. Thermal stabilities and decomposition products of the complexes were investigated in the temperature range 40-700 degrees C in the static air atmosphere. (C) 2017 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.molstruc.2017.02.013
dc.identifier.endpage287
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85012180392
dc.identifier.scopusqualityQ1
dc.identifier.startpage281
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2017.02.013
dc.identifier.urihttps://hdl.handle.net/11486/6396
dc.identifier.volume1136
dc.identifier.wosWOS:000397375800029
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectTetracyanometallate complex
dc.subject4-(2-aminoethyl)pyridinium complex
dc.subjectC-H center dot center dot center dot M interaction
dc.subjectHydrogen bond interaction
dc.subjectCrystal structure
dc.subjectVibrational spectra
dc.titleSynthesis, spectroscopic, thermal and structural properties of 4-(2-aminoethyl)pyridinium tetracyanometallate(II) complexes
dc.typeArticle

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