Nine new tetracyanometallate(II) complexes with 2-(2-aminoethyl)pyridine: synthesis, crystal structures and spectroscopic studies

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dc.authoridKURKCUOGLU, GUNES SUHEYLA/0000-0003-3945-3085
dc.contributor.authorKurkcuoglu, Gunes Suheyla
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorSayin, Elvan
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:35:23Z
dc.date.available2025-03-23T19:35:23Z
dc.date.issued2022
dc.departmentSinop Üniversitesi
dc.description.abstractNine new cyanide complexes, {[Cu(aepy)(2)M(mu-CN)(CN)(3)]center dot 2H(2)O}(n) [M(II) = Ni (1), Pd (2) or Pt (3)], [Zn(aepy)(2)M(mu-CN)(CN)(3)](n) [M = Ni (4), Pd (5) or Pt (6)] and [Cd(aepy)(2)M(mu-CN)(CN)(3)](n) [M(II) = Ni (7) or Pd (8)] and (Haepy)(2)[Pt(CN)(4)] (9) (aepy = 2-(2-aminoethyl)pyridine), were synthesized and characterized structurally using single crystal X-ray diffraction, vibrational spectroscopy, thermal and elemental analyses. The structure analyses revealed that cyanide complexes 1-3 for Cu(II) and 4-6 for Zn(II) are heterobinuclear clusters, whereas the two Cd(II) complexes 7 and 8 are infinite one-dimensional coordination polymers. In heterometallic complexes 7 and 8, the Cd(II) ions are located on a center of symmetry and are coordinated by two nitrogens from cyanide ligands and four nitrogens from aepy ligands, thus showing a distorted octahedral geometry. In 1-9, the intermolecular N-H center dot center dot center dot N hydrogen bonds or/and C-H center dot center dot center dot M interactions (M = Ni(II), Pd(II) and Pt(II)) generate 3D supramolecular networks.
dc.description.sponsorshipEskisehir Osmangazi University, Scientific research Unit [201919018]
dc.description.sponsorshipThis work has been financially supported by Eskisehir Osmangazi University, Scientific research Unit (Grant No. 201919018).
dc.identifier.doi10.1080/00958972.2022.2096449
dc.identifier.endpage1373
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue9-10
dc.identifier.scopus2-s2.0-85134037192
dc.identifier.scopusqualityQ3
dc.identifier.startpage1352
dc.identifier.urihttps://doi.org/10.1080/00958972.2022.2096449
dc.identifier.urihttps://hdl.handle.net/11486/5857
dc.identifier.volume75
dc.identifier.wosWOS:000823832800001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectTetracyanometalate(II) complexes
dc.subject2-(2-Aminoethyl) pyridine complexes
dc.subjectCyanide complexes
dc.subjectHeteronuclear complexes
dc.subjectC-H center dot center dot center dot M interaction
dc.titleNine new tetracyanometallate(II) complexes with 2-(2-aminoethyl)pyridine: synthesis, crystal structures and spectroscopic studies
dc.typeArticle

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