Synthesis, characterization, crystal structure, redox-reactivity and antiproliferative activity studies of Cu(II) and Pd(II) complexes with F, CF3 bearing 3,5-di-tert-butylsalicylaldimines

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dc.authoridGumushan Aktas, Hatice/0000-0002-6650-184X
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.contributor.authorKasumov, Veli T.
dc.contributor.authorSahin, Onur
dc.contributor.authorAktas, Hatice Gumushan
dc.date.accessioned2025-03-23T19:38:20Z
dc.date.available2025-03-23T19:38:20Z
dc.date.issued2016
dc.departmentSinop Üniversitesi
dc.description.abstractIn this work, based on 3,5-di-tert-butyl-2-hydroxybenzaldehyde and F, CF3-substituted anilines [2-fluoro-3-(trifluromethyl)aniline, 2-fluoro-5-(trifluromethyl)aniline, 3,5-bis(trifluoromethylaniline and 2-fluoro-3-(trifluromethyl)benzylaniline], the corresponding salicylaldimine ligands (HLx, X = 1, 2, 3, 4) and their CuL2x and PdL2x complexes were synthesized. The structures of these compounds were characterized by spectroscopic (IR, UV/Vis, H-1 and F-19 NMR, ESR) and X-ray diffraction techniques. Chemical oxidation of the tert-buylated HLx ligands and their CuLx2 complexes using Ce(IV) under anaerobic and aerobic conditions at room temperature (r.t.) in DMF solution revealed the generation of phenoxyl radicals. An X-ray structural study revealed that thanks to CH....F and CH.....pi bonds both the CuL21 and PdL21 molecules crystallize as hydrated dimers that pack differently. The antiproliferative potentials of all the compounds against Mat-LyLu cell lines were determined. (C) 2016 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipHarran University Research Fund (HUBAK)
dc.description.sponsorshipThe authors would like to acknowledge financial support from Harran University Research Fund (HUBAK).
dc.identifier.doi10.1016/j.poly.2016.03.061
dc.identifier.endpage127
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-84971013906
dc.identifier.scopusqualityQ2
dc.identifier.startpage119
dc.identifier.urihttps://doi.org/10.1016/j.poly.2016.03.061
dc.identifier.urihttps://hdl.handle.net/11486/6127
dc.identifier.volume115
dc.identifier.wosWOS:000382349000016
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectF,CF3Ph-salicylaldimines
dc.subjectX-ray
dc.subjectCu-II-phenoxyl
dc.subjectAntiproliferative activity
dc.subjectRedox reactivity
dc.titleSynthesis, characterization, crystal structure, redox-reactivity and antiproliferative activity studies of Cu(II) and Pd(II) complexes with F, CF3 bearing 3,5-di-tert-butylsalicylaldimines
dc.typeArticle

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