The synthesis, characterization, and theoretical hydrogen gas adsorption properties of copper(II)-3,3′-thiodipropionate complexes with imidazole derivatives

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dc.authoridkeskin, seda/0000-0001-5968-0336
dc.authoridArici, Mursel/0000-0001-8527-1587
dc.contributor.authorArici, Mursel
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorKeskin, Seda
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2025-03-23T19:35:27Z
dc.date.available2025-03-23T19:35:27Z
dc.date.issued2013
dc.departmentSinop Üniversitesi
dc.description.abstractThree new coordination polymers, [Cu((3)-tdp)(im)(2)](n) (1), {[Cu((3)-tdp)(1-mim)(2)]0.5H(2)O}(n) (2) and {[Cu-2((3)-tdp)(2)(4-mim)(4)]H2O}(n) (3) [tdpH(2)=3,3-thiodipropionic acid, im=imidazole, 1-mim=1-methylimidazole and 4-mim=4-methylimidazole], have been prepared and characterized by spectroscopic techniques (IR and UV-Vis), elemental analyzes, magnetic measurements, thermal analyzes, and single-crystal X-ray diffraction. Complexes 1-3 crystallize in the monoclinic system with space groups of C2/c and P2(1)/c, respectively. In 1-3, tdp is a bridging ligand to form 1-D chains, which are extended into a 2-D layer by hydrogen bonding and interactions. The 3,3-thiodipropionate exhibits an unexpected coordination mode in 1-3. Simulations were used to assess the potential of the complexes in H-2 storage applications.
dc.description.sponsorshipScientific Research Fund of Eskisehir Osmangazi University [201219A101]
dc.description.sponsorshipThis work was supported by the Scientific Research Fund of Eskisehir Osmangazi University [Project number 201219A101].
dc.identifier.doi10.1080/00958972.2013.860223
dc.identifier.endpage4106
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue23
dc.identifier.scopus2-s2.0-84890486953
dc.identifier.scopusqualityQ3
dc.identifier.startpage4093
dc.identifier.urihttps://doi.org/10.1080/00958972.2013.860223
dc.identifier.urihttps://hdl.handle.net/11486/5872
dc.identifier.volume66
dc.identifier.wosWOS:000328193200003
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subject33-Thiodipropionic acid
dc.subject33-Thiodipropionate complexes
dc.subjectImidazole complexes
dc.subjectCopper(II) complexes
dc.titleThe synthesis, characterization, and theoretical hydrogen gas adsorption properties of copper(II)-3,3′-thiodipropionate complexes with imidazole derivatives
dc.typeArticle

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