Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline

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dc.contributor.authorUçar, Asuman
dc.contributor.authorFındık, Mükerrem
dc.contributor.authorKocak, Nuriye
dc.contributor.authorÇolak, Alper Tolga
dc.contributor.authorŞahin, Onur
dc.date.accessioned2025-03-23T19:11:54Z
dc.date.available2025-03-23T19:11:54Z
dc.date.issued2021
dc.departmentSinop Üniversitesi
dc.description.abstractHerein a novel inorganic-organic hybrid Keggin-type heteropolymolybdate [Ni2Na(C12H8N2)4(BMo12O40)(H2O)2] (1) has been synthesized under hydrothermal conditions in aqueous solution. The cyrstal structure was fully characterized by powder X-ray diffraction (XRD), elemental analysis, Fourier-tranform infrared spectrum (FT-IR), Thermogravimetric analysis (TGA) and Scanning Electron Microscopy (SEM) analysis. Single crystal X-ray structural analysis demonstrates that the complex consists of a Keggin anion [BMo12O40]5− polyanion, four 1,10-phenanthroline (C12H8N2) ligands, two Ni(II) ions, two Na(I) ions and two aqua ligands. The experimental powder X-ray diffraction (XRD) result of the crystal is consistent with the calculated data. The SEM image shows that the compound crystals have a cubic structure.
dc.identifier.doi10.17776/csj.812164
dc.identifier.endpage29
dc.identifier.issn2587-2680
dc.identifier.issn2587-246X
dc.identifier.issue1
dc.identifier.startpage22
dc.identifier.trdizinid1120627
dc.identifier.urihttps://doi.org/10.17776/csj.812164
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/1120627
dc.identifier.urihttps://hdl.handle.net/11486/3693
dc.identifier.volume42
dc.indekslendigikaynakTR-Dizin
dc.language.isoen
dc.relation.ispartofCumhuriyet Science Journal
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_TR_20250323
dc.subjectKimya
dc.subjectİnorganik ve Nükleer
dc.titleHydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline
dc.typeArticle

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