A Crystallographic, EPR and DFT Investigations of a Novel Magnetically Silent Mono-atom Acetate-Bridged Binuclear Schiff Base-Copper(II) Complex

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dc.contributor.authorDemir, Serkan
dc.contributor.authorYerli, Yusuf
dc.contributor.authorÖztürk, Mustafa
dc.contributor.authorSaral, Hasan
dc.contributor.authorTemel, Ersin
dc.contributor.authorBaşgel, Serkan
dc.date.accessioned2025-03-23T19:12:16Z
dc.date.available2025-03-23T19:12:16Z
dc.date.issued2017
dc.departmentSinop Üniversitesi
dc.description.abstractA recent example of one-atom acetate bridged symmetric dinuclear copper(II) complexes, Di-µ-acetato-bis{1- ((pyridin-2-ylmethylimino)methyl)naphthoxo}copper(II) ([Cu2(NP)2(Ac)2]•2MetOH(1)) (HNP=1-((pyridin-2- ylmethylimino)methyl)naphthol)) have been prepared and characterized by X-ray crystallography, Elemental analyses, ESI-mass, UV-Vis and IR spectroscopic techniques. Magnetic properties of the complex have been probed by EPR measurements and the presence of spin-only paramagnetism of the compound with none of significant exchange coupling has been demonstrated unlike ferro or antiferromagnetism that was otherwise observed in all other analogous structures previously reported. The existence of a trivial ferromagnetic exchange which is quantitatively ignorable has been suggested by DFT-Broken Symmetry calculations performed at crystallographically characterized experimental geometry.
dc.identifier.doi10.15671/HJBC.2017.136
dc.identifier.endpage9
dc.identifier.issn1303-5002
dc.identifier.issn2687-475X
dc.identifier.issue1
dc.identifier.startpage1
dc.identifier.trdizinid286527
dc.identifier.urihttps://doi.org/10.15671/HJBC.2017.136
dc.identifier.urihttps://search.trdizin.gov.tr/tr/yayin/detay/286527
dc.identifier.urihttps://hdl.handle.net/11486/3780
dc.identifier.volume45
dc.indekslendigikaynakTR-Dizin
dc.language.isoen
dc.relation.ispartofHacettepe Journal of Biology and Chemistry
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_TR_20250323
dc.subjectSpektroskopi
dc.subjectFizikokimya
dc.subjectKimya
dc.subjectİnorganik ve Nükleer
dc.titleA Crystallographic, EPR and DFT Investigations of a Novel Magnetically Silent Mono-atom Acetate-Bridged Binuclear Schiff Base-Copper(II) Complex
dc.typeArticle

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