Synthesis, Spectral and Thermal Studies, and Crystal Structure of cis-Bis(4-methylimidazole)bis(picolinato)copper(II) [Cu(pic)2(4-MeIm)2]

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dc.contributor.authorHeren, Zerrin
dc.contributor.authorKeser, Cem
dc.contributor.authorErsanlı, Cem Cüneyt
dc.contributor.authorYeşilel, O. Zafer
dc.contributor.authorOcak, Nazan
dc.date.accessioned2014-08-25T13:23:22Z
dc.date.available2014-08-25T13:23:22Z
dc.date.issued2006
dc.description.abstractThe mixed-ligand picolinato (pic) complex of Cu(II) with 4-methylimidazole (4-MeIm),[Cu(pic) 2 (4-MeIm) 2], was synthesized and characterized by elemental analysis, magnetic susceptibility, spectroscopic methods (UV/vis and FT-IR) and X-ray diffraction. In the slightly distorted octahedral cis-bis(4-methylimidazole)bis(picolinato)copper(II) complex, the pic ligands are coordinated to the Cu(II) ion as bidentate N,O-donors forming chelate rings. The 4-MeIm ligands are N-coordinated in cis positions. The complex crystallizes in the triclinic space group P?1 with unit cell parameters a=9.204(5), b=9.498(5),c=13.095(5)?A, ?=90.395(5), ?=101.687(5), ?=112.291(5)?andZ=2. ydrogen bondings and C-H···?interactions occur between picolinato and methylimidazoleligands of eighboring complex molecules. The thermal decomposition of the complex is described
dc.identifier.citationHeren, Z., Keser, C., Ersanlı, Cem C., Yeşilel, O. Z., Ocak, N. "Synthesis, Spectral and Thermal Studies, and Crystal Structure of cis-Bis(4-methylimidazole)bis(picolinato)copper(II) [Cu(pic)2(4-MeIm)2]". Zeitschrift für Naturforschung B, 61b, 1217–1221.
dc.identifier.issn0932-0776
dc.identifier.urihttp://www.znaturforsch.com/ab/v61b/s61b1217.pdf
dc.identifier.urihttps://hdl.handle.net/11486/451
dc.language.isoen
dc.publisherZeitschrift für Naturforschung B
dc.relation.publicationcategoryMakale - Kategorisiz
dc.subjectCopper(II) Complex
dc.subject4-Methylimidazole
dc.subjectPicolinic Acid
dc.subjectThermal Decomposition
dc.titleSynthesis, Spectral and Thermal Studies, and Crystal Structure of cis-Bis(4-methylimidazole)bis(picolinato)copper(II) [Cu(pic)2(4-MeIm)2]
dc.typeArticle

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