Dimethyl sulfoxide Species Entrapped by Raw and Acid-Activated Sepiolite Framework

dc.contributor.authorTabak, Ahmet
dc.contributor.authorAfsin, Beytullah
dc.contributor.authorÇaglar, Bülent
dc.contributor.authorÇaglar, Sema
dc.date.accessioned2025-03-23T18:52:45Z
dc.date.available2025-03-23T18:52:45Z
dc.date.issued2016
dc.departmentSinop Üniversitesi
dc.description.abstractNovel hybridorganic-clay materials were prepared by interaction of dimethyl sulfoxidemolecules in the interlayer space of raw and acid activated sepiolitecomposites. The structural and thermal properties of the hybrid materials, raw andacid activated sepiolite were examined by using Fourier transform infrared, thermalanalysis, X-ray powder diffraction and surface area measurement techniques. Thermalanalysis data prove the remarkable effects of acid activation on the frameworkof sepiolite which are reflected by the intercalation mechanism proceedingthrough the replacement partly of the interstitial water by dimethyl sulfoxidespecies. The protons are directly involved in the actual structure and thusenhances the thermal stability of the complex between dimethyl sulfoxide andthe sepiolite. The noticeable surface area increase of activated sepiolite thanthat of the raw one is connected to the micropore formation. The data presentedin this study may also provide further insight into catalysis studies and theapplication of clays in the growing field of environmental management.
dc.identifier.endpage82
dc.identifier.issn2536-4383
dc.identifier.issn2564-7873
dc.identifier.issue1
dc.identifier.startpage76
dc.identifier.urihttps://hdl.handle.net/11486/2005
dc.identifier.volume1
dc.language.isoen
dc.publisherSinop Üniversitesi
dc.relation.ispartofSinop Üniversitesi Fen Bilimleri Dergisi
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_DergiPark_20250323
dc.subjectdimethyl sulfoxide
dc.subjectsepiolite
dc.subjectinterstitial water
dc.titleDimethyl sulfoxide Species Entrapped by Raw and Acid-Activated Sepiolite Framework
dc.typeArticle

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