Heteronuclear cadmium(II)/cobalt(III) cyanide coordination polymers with 1-methylimidazole and 1-ethylimidazole ligands: synthesis, characterization and activities

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dc.contributor.authorKurkcuoglu, Guenes Sueheyla
dc.contributor.authorKekec, Seray
dc.contributor.authorYesilel, Okan Zafer
dc.contributor.authorGokkus, Kutalmis
dc.contributor.authorUnver, Hakan
dc.contributor.authorSahin, Onur
dc.date.accessioned2025-03-23T19:41:30Z
dc.date.available2025-03-23T19:41:30Z
dc.date.issued2025
dc.departmentSinop Üniversitesi
dc.description.abstractTwo new heteronuclear Cd(II)/Co(III) compounds, {[Cd(1-meim)3Cd0.5(1-meim)Co(mu-CN)4(CN)2]}n 3 Cd 0 . 5 (1-meim)Co(mu-CN) 4 (CN) 2 ]} n (1) 1 ) and {[Cd(1-etim)3Cd0.5(1-etim)2Co(mu-CN)3(CN)3]& sdot;H2O}n 3 Cd 0 . 5 (1-etim) 2 Co(mu-CN) 3 (CN) 3 ] & sdot; H 2 O} n (2) 2 ) (1-meim: 1-methylimidazole, 1-etim = 1-ethylimidazole), have been synthesized and characterized using elemental analysis, FT-IR and Raman spectroscopy, single-crystal X-ray diffraction techniques. The single crystal X-ray study shows that the compound 1 exhibited a 1D double chain structure and is further linked into 3D supramolecular architectures through C-H & sdot;& sdot;& sdot;N - H & sdot;& sdot;& sdot; N and it & sdot;& sdot;& sdot;it & sdot;& sdot;& sdot; it interactions. Whereas the compound 2 displayed 2D network which is extended into a 3D supramolecular framework by O-H & sdot;& sdot;& sdot;N - H & sdot;& sdot;& sdot; N hydrogen bonds and C-H center dot center dot center dot it - H center dot center dot center dot it interactions. In 1 and 2 , each Co(III) ion is coordinated by six carbon atoms from cyanide ligands, thus showing an octahedral coordination geometry. Cd1 and Cd2 ions exhibited two different geometries, distorted trigonal bipyramidal and octahedral. Furthermore, phase purities, catalytic and thermal properties were investigated.
dc.description.sponsorshipEskisehir Osmangazi University, Scientific research Unit [2022-2561]
dc.description.sponsorshipThis work has been financially supported by Eskisehir Osmangazi University, Scientific research Unit (Grant No: 2022-2561) .
dc.identifier.doi10.1016/j.ica.2024.122400
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1016/j.ica.2024.122400
dc.identifier.urihttps://hdl.handle.net/11486/6597
dc.identifier.volume574
dc.identifier.wosWOS:001333879600001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofInorganica Chimica Acta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectHexacyanocobaltate(III) complex
dc.subject1-Methylimidazole complex
dc.subject1-Ethylimidazole complex
dc.subjectCadmium(II) complex
dc.subjectCoordination polymer
dc.subjectHydrogen production
dc.subjectThymol oxidation
dc.titleHeteronuclear cadmium(II)/cobalt(III) cyanide coordination polymers with 1-methylimidazole and 1-ethylimidazole ligands: synthesis, characterization and activities
dc.typeArticle

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