Investigation of Electrochemical Behaviour of 3-Allyl-4-Hydroxy-3′-4′-Dimethylazobenzene

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dc.authoridKARAMAN, Yeliz/0000-0003-1792-5037
dc.authoridTOPCU, Saim/0000-0002-1169-6037
dc.contributor.authorMenek, Necati
dc.contributor.authorBasaran, Serpil
dc.contributor.authorKaraman, Yeliz
dc.contributor.authorTopcu, Saim
dc.date.accessioned2025-03-23T19:48:24Z
dc.date.available2025-03-23T19:48:24Z
dc.date.issued2013
dc.departmentSinop Üniversitesi
dc.description.abstractThe reductive voltammetric and polarographic behaviour of the 3-allyl-4-hydroxy-3'-4'-dimethylazobenzene at a hanging mercury drop electrode (HMDE) and static mercury drop electrode (SMDE) has been studied in Britton-Robinson (B-R) buffers in the pH range of 2.0-12.0. The 3-allyl-4-hydroxy-3'-4'-dimethylazobenzene gave one voltammetric and polarographic peak, corresponding to the reduction of the azo group to hydrazo and amine. The reduction process was found to be dependent on the pH of the supporting electrolyte. The reduction of the azo group to amino group in acidic media and hydrazo step in neutral and basic media was observed. From the observation an electrode reaction mechanism has been suggested for the compound.
dc.identifier.endpage6407
dc.identifier.issn1452-3981
dc.identifier.issue5
dc.identifier.scopusqualityQ3
dc.identifier.startpage6399
dc.identifier.urihttps://hdl.handle.net/11486/7576
dc.identifier.volume8
dc.identifier.wosWOS:000319861000033
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.language.isoen
dc.publisherEsg
dc.relation.ispartofInternational Journal of Electrochemical Science
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250323
dc.subjectVoltammetry
dc.subjectpolarography
dc.subjectazo dyes
dc.subjectreduction mechanism
dc.titleInvestigation of Electrochemical Behaviour of 3-Allyl-4-Hydroxy-3′-4′-Dimethylazobenzene
dc.typeArticle

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