Shah, Javed HussainShahbaz, MuhammadSharif, ShahzadUllah, GhulamShahzad, SundasMunawar, Khurram ShahzadSahin, Onur2025-03-232025-03-2320250025-54081873-4227https://doi.org/10.1016/j.materresbull.2024.113123https://hdl.handle.net/11486/6456In this research study, we have synthesized, characterized and extensively compared the electrochemical characteristics of two materials derived from 5-sulphoisophtalic acid, 4,4-bipyridine and cobalt metal using sonochemical method. Cobalt-bipyridine complex with 5-SIP in lattice structure (RG-41) showed predominant capacitive behavior whereas Co-SIP-Bpy MOF (RG-42) exhibited significant pseudocapacitive attributes due to the presence of coordination linkage responsible for the electron transfer. Due to the effective electrochemical properties of RG-42, we implemented it practically by fabricating a hybrid device with outstanding electrochemical features, demonstrating impressive 92 % cyclic stability with energy density and power density of 51.41 Wh/kg and 800 W/kg at 1 A/g, respectively. Dunn's method was employed to obtain capacitive-diffusive contributions for both half-electrochemical cells as well as hybrid device. These results underscored the potential of RG-42 as a competitive electrode material for future energy storage applications.eninfo:eu-repo/semantics/closedAccessHybrid supercapacitorCapacitive behaviorCyclic stabilityEnergy densityPower densityDunn's methodEnergy storageArticle18110.1016/j.materresbull.2024.1131232-s2.0-85205482480Q1WOS:001333176100001Q2